Structure and thermal properties of as-fabricated U-7Mo/Mg and U-10Mo/Mg low-enriched uranium research reactor fuels

Abstract

Aluminum-clad U-7Mo/Mg and U-10Mo/Mg pin-type mini-elements (with a core uranium loading of 4.5 gU/cm3) have been fabricated at the Canadian Nuclear Laboratories for experimental tests and ultimately for use in research and test reactors. In this study, the microstructure and phase composition of unirradiated U-7Mo/Mg and U-10Mo/Mg fuel cores were analyzed using optical and scanning electron microscopy, and neutron powder diffraction. Thermal properties were characterized using a combination of experimental measurements and thermodynamic calculations. The thermal diffusivity was measured using the laser flash method. The temperature-dependent specific heat capacities were calculated based on the linear rule of mixture using the weight fraction of different crystalline phases and their specific heat capacity values taken from the literature. The thermal conductivity was then calculated using the measured thermal diffusivity, the measured density and the calculated specific heat capacity. The resulting thermal conductivity is practically identical for both types of fuel. The in-reactor temperatures were predicted using conjugate heat transfer simulations.