Abstract
The crystal structures of the compounds [M(NMTP)] 4 (BF 4 ) 2 (M=Zn 2+ , Ni 2+ ; NMTP=N-methyl-2-thioxopyrrolidine) are reported. Whereas the zinc(II) complex has a nearly regular tetrahedral geometry, the nickel(II) complex is significantly distorted in the manner predicted by the Jahn-Teller theorem, with trans-SNiS angles decreasing from the tetrahedral value of 109.5 to 85 o . Metal-ligand bonding parameters have been derived from an analysis of the optical spectrum of [Ni(NMTP)] 4 (BF 4 ) 2
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
