Abstract

A series of MoO3/t-ZrO2 catalysts was prepared by slurry deposition. Structural studies revealed that the presence of MoO3 had no influence on the phase composition of zirconia support. IR/RS and EPR results confirmed that both isolated and polymeric (2D) oxomolybdenum species occurred on catalysts surface. Adsorption of NO resulted in the reduction of molybdenum centers with simultaneous formation of surface nitrates.

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