Abstract

The complex [UO2(SeO4)(C5H12N2O)2(H2O)] (I) was synthesized and studied by thermal analysis, IR spectroscopy, and X-ray crystallography. The crystals are orthorhombic: a = 13.1661(3) A, b = 16.4420(5) A, c = 17.4548(6) A, Pbca, Z = 8, R = 0.0423. The structural units of crystal I are chains with the composition coinciding with that of the compounds of the AB2M31 crystal chemical group of the uranyl complexes (A = UO22+, B2 = SeO42−, M1 = C5H12N2O and H2O).

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