Abstract
The previously undescribed 3-(1-hydroxy-4-bromo-2-naphthyl)propenal was synthesized. This aldehyde exists primarily in the form of the cyclic 2H-chromene tautomer in the crystalline state, in solutions in nonpolar solvents, and in acetonitrile, ethanol, and acetone. Ring-chain tautomeric equilibrium between the 2H-chromene and quinoid structures is observed in dimethyl sulfoxide.
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