Abstract
A paramagnetic, pentanuclear, metal-metal bonded complex comprising three metals is isolated. The Cu dx2-y2 orbital of the Rh-Pt-Cu-Pt-Rh chain contains an unpaired electron. The close energetic levels and symmetric overlap of the Cu dx2-y2 and Rh-Pt δ* induces a charge-transfer reaction to achieve the diamagnetic Rh-Pt-Cu-Pt-Rh complex.
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