Abstract

Work on the block polymers of styrene and butadiene indicates the potential of multiphase polymers of controlled solid state structure. The effect of chemical composition, molecular architecture (multichain ‘star’ shaped versus linear), block sequence length, processing conditions, and blending of homopolymer with the block polymers on their solid state morphology is discussed. Results on these block polymer systems indicate the future research directions in certain areas. Implications of these areas for polymers of controlled solid state structure to provide materials of desirable combination of properties are also considered.

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