Abstract
The glass-forming region in the BiO 1.5BaOCuO system was determined, and the structure and crystallization of the glasses were investigated and compared to glasses containing CaO or SrO in place of BaO. It has been found that the glass-forming region in this system is wider than those in the BiO 1.5CaOCuO and BiO 1.5SrOCuO systems. BaBiO 2.77 was preferentially formed in the first stage of crystallization at all glass compositions. It is suggested that the Ba 2+ ions may preferentially occupy the sites near BiO 6 octahedra, while the Ca 2+ ions in BiO 1.5CaOCuO glasses may not have a site preference with respect to the BiO 6 octahedra.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
