Abstract
Chemical oxidation of a TTF-based NiII complex with I2 produces the corresponding radical cation salt1, [Ni2Cl2(L)2](I3)2(I5)2(I2)(H2O)2(C4H8O)3, (L=4,5-bis(2-pyridylmethylsulfanyl)-4′,5′-ethylenedithiotetrathiafulvalene). The results of magnetic susceptibility measurements show the occurrence of intramolecular magnetic exchange interactions in1. The lack of close S…S contacts, confirmed by crystal structure analysis, results in an insulating behavior.
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