Abstract
A novel branch-like one-dimensional supramolecular network structure is constructed from the self-assembly of copper(II) azamacrocyclic complex with azetidine group and iron(III) hexacyanide and it shows a weak ferromagnetic coupling between the copper(II) and iron(III) ions. The one-dimensional coordination polymer like fern branch, [Cu II (L)] 3 [Fe III (CN) 6 ] 2 ·8H 2 O ( 1 ), which is linked by azamacrocyclic copper(II) complex and iron(III) hexacyanide, has been synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility measurement (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane). Compound 1 shows a weak ferromagnetic coupling between the copper(II) and low spin iron(III) ions in the one-dimensional chain structure.
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