Abstract
One new three-dimensional Cd(II) polymer [Cd3(MMA)2(INA)2]n (1) was synthesized hydrothermally based on mixed flexible methylmalonic acid (H2MMA) and rigid isonicotinic acid (HINA) ligands. Single-crystal X-ray diffraction analysis reveals that compound 1 has a 3D framework structure consisting of 2D {Cd3} layer unit and INA− connector, which bears a (3,8)-connected tfz-d topology with Schläfli symbol of {43}2{46.618.84}. The solid-state luminescent property was studied and 1 exhibits strong emission centered at 429nm.
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