Structure and hydrogen absorption properties of Ti53Zr27Ni20(Pd,V) quasicrystals

Abstract

The structure and hydrogen absorption properties of Pd and V doped TiZrNi quasicrystals were investigated in terms of the equilibrium vapor pressure of hydrogen, and the results were compared with those of undoped samples. Rapidly quenched Ti53Zr27Ni20 alloys formed quasicrystals and absorbed hydrogen H/M (hydrogen to host metal atom ratio) value of 1.79 at room temperature. This was attributed to their structure, which contains mostly tetrahedral interstitial sites that are chemically formed by atoms having a high affinity with hydrogen. However, the relatively low equilibrium vapor pressure of hydrogen, 0.14 Torr at 300 °C, prevents TiZrNi quasicrystals for the practical application on energy storage materials. To overcome this limitation, we replaced Ti with Pd and V to increase the vapor pressure of hydrogen and investigated the properties of hydrogen absorption behaviors. Results of XRD measurements revealed that the quasicrystal structure was maintained by the replacement of Ti with a maximum of 8 at. % of Pd and V. Total amounts of the absorbed hydrogen decreased from 1.33 to 1.06 and to 1.12 of the H/M values when the Ti was replaced by 8 at. % of Pd and V, respectively, at 300 °C. The pressure-composition-temperature data measured using an automatic gas-handling system revealed that the equilibrium vapor pressure increased from 0.14 to 0.21 and to 0.56 Torr at H/M value of 0.5 when Ti atoms were replaced by 8 at. % Pd, and V, respectively, without the appearance of an impurity phase. Our results demonstrate that the replacement of Ti with Pd and V is an effective method to increase the equilibrium vapor pressure of hydrogen without a phase transformation in a TiZrNi quasicrystal system.