Abstract

An O-polysaccharide was obtained by mild acid degradation of the lipopolysaccharide of Salmonella enterica O60 strain G1462, and the following unique structure of the O-unit was determined by chemical analyses along with 2D 1H and 13C NMR spectroscopy: [Display omitted] where Fuc3NFo stands for 3-formamido-3,6-dideoxygalactose. The structure established is in agreement with the O-antigen gene cluster of S. enterica O60, which contains putative genes for the synthesis of GDP- d-Man and dTDP- d-Fuc3NFo, three glycosyltransferase genes, and two O-unit-processing genes ( wzx and wzy).

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