Abstract
The structure and dynamics of the guest molecules in cyclophosphazene inclusion compounds are studied by 2H and 13C NMR spectroscopy. Despite the rather strong molecular constraints imposed by the host lattice, the guest species are highly mobile, comprising both overall reorientational and internal conformational motions. It is found that the conformational equilibria of monosubstituted cyclohexanes bearing polar substituents are significantly altered by the incorporation into the cyclophosphazene host channels.KeywordsGuest MoleculeInclusion CompoundConformational EquilibriumGuest SpeciesPolar SubstituentThese keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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