Abstract
The structure and the internal dynamics of the lactam 1,3-dimethyl-2-imidazolidinone, also known as N,N′-dimethylethyleneurea, have been investigated through the analysis of its free-jet absorption rotational spectrum. One conformer has been assigned. The pure μb-type spectrum, recorded in the 59.6–74.4GHz frequency range entails an inertial defect Δc=−16.39uÅ2, indicating that the molecule has C2 symmetry with a twisted arrangement of the ring. The methyl internal rotation barrier V3=7.181 (3)kJmol−1 and the 14N diagonal nuclear quadrupole coupling constants χaa=2.14 (14) and (χbb-χcc)=7.26 (6)MHz were determined from the analysis of the hyperfine structure. They are in good agreement with the ab initio MP2/6-311++G(d,p) calculations which also estimate the electric dipole moment value as 3.9 D.
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