Abstract

Alkylacrylate copolymers ▪ form a myelinic phase showing vesicles ∼1000 A ̊ in diameter and a minimum thickness of 30 Å. Electron microscope and diffraction patterns show that the membrane is a monolayer of the hexagonal stacking of the C 22 alkyl chains. A structural model is proposed showing how the alkylchains are connected by the principal polymer chain. The growth mechanism of such vesicles is discussed.

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