Abstract
The structures of the [{Ru(CO) 2(μ-OOCCH 3)L} 2] with L = P nBu 3, P tBu 3 or P iPr 3 have been determined and their catalytic activity tested in the hydrogenation of internal and terminal olefins, of the carbonyl double bond and of both free and esterified carboxylic groups. There is a correlation between the PRuRuP torsion angle and the catalytic activity of the complex.
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