Abstract
The length of the carbon bridge between the two positively charged nitrogen centers in dication 1 influences the coordination sphere of the Bi center in the title anion. The change from square-pyramidal (n = 3, shown schematically on the right) to pentagonal-pyramidal (n = 2) is attributed to the formation of NHO hydrogen bonds.
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More From: Angewandte Chemie International Edition in English
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