Abstract
The structures of holmium-organophosphorus mono- and bidentate ligands and uranium-monoamide ligand complexes in solutions were determined by extended X-ray absorption fine-structure spectroscopy. The diphosphine dioxide coordinates directly to holmium with symmetric bidentate mode, while the carbamoyl phosphine oxide with asymmetric bidentate mode. The structure for uranium- N, N-dihexyl-3-ethylhexanamide complex is very similar to that for the aqua nitrato uranyl complex in bond distance and coordination number.
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