Abstract
The vapour above heated ferric chloride (Fe2Cl6) been isolated in nitrogen, argon and neon matrices. The XANES features are indicative of iron in a tetrahedral environment and the interatomic distances from the EXAFS data for the nearest neighbour shells are in good agreement with the vapour phase electron diffraction data. In the case of the nitrogen matrix isolated species the Fe...Fe distance has been determined, indicating the potential usefulness of matrix XAS for the study of vapour phase intermediates. The reasons for the non-observance of this shell in argon and neon matrices are considered.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
