Abstract

AbstractThe preparation, characterisation and single‐crystal XRD molecular structure determinations of the three Ru3 carbonyl clusters attached to carbon ligands, Ru3(μ‐H)3(μ3‐CBr)(CO)9 (1), Ru3(μ‐H)(μ‐dppm){μ‐C(OMe)}(CO)8 (2) and AuRu3(μ‐H)2(μ3‐C=C=CHPh)(CO)10 (3) are reported, together with the structures of the tetranuclear hydrido‐carbonyls Ru4(μ‐H)4–2x(CO)11+x(PPh3) (x = 0 4, 1 5).

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