Abstract

Raman scattering measurements have been performed on a series of a-Si:H/a-SiN x:H multilayer films with hydride layer thickness d varying from 8 – 90Å. The results show that with decreasing thickness the hydride layers become progressively more disordered. This increasing bond angle disorder is attributed to an additional distortion in the amorphous network near the interface which arises from the mismatch in the interatomic distances between a-Si:H and a-SiN x:H. A comparison of the results for the multilayers with those for thick films of a-Si and a-Ge shows that for small layer thicknesses the interface induced disorder can significantly affect the properties of the hydride layer.

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