Abstract
The structure of a novel expolysaccharide obtained from a mutant of Rhizobium meliloti strain Rm1021 was elucidated by a combination of enzymic, chemical, and spectroscopic methods. The polysaccharide is composed of a disaccharide repeating-unit, β- d-Glc p-(1→3)-α- d-Gal p-(1→3), having a 6- O-acetyl group attached to most d-glucose residues and a 4,6- O-(1-carboxyethylidene) group attached to every d-galactose residue.
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