Abstract

A simple analytical approach for the calculation of the phase diagram for polymorphic fcc-bcc transition in systems with isotropic repulsive potentials is proposed. A comparison of the proposed approach with the existing numerical and theoretical data is presented for Yukawa and inverse-power potentials: the emphasis is on the Yukawa model. The influence of the non-linearity (of anharmonic corrections) of the pair interaction forces on the phase-equilibrium curves for fcc-bcc and solid-liquid phase transitions is considered.

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