Abstract
A single EPR line of isotropic and Lorentzian form was observed in a crystal of NiCl 22H 2O between 113 and 300 K. During a cooling run a sudden line broadening was observed at 200 K associated with a known crystallographic phase transition. On heating, the corresponding transition temperature was 220 K. The EPR spectra are interpreted in terms of a modified Anderson and Weiss model. The crystal field parameter is determined as D = 0.81 K and D = 1.07 K above and below the transition temperature, respectively.
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