Abstract

Results obtained by the method of isotopic substitution in neutron diffraction on the structural ordering in the glassy semiconductor g − (Ag2Te)0.5(As2Te3)0.5show that the short-range order of the network former (g − As2Te3) is retained and the Ag-Ag intermediate-range order is similar to that of the crystalline network modifier (c − Ag2Te). By comparison with results for the glassy fast-ion conductorg − (Ag2Se)0.25(AsSe)0.75 it is concluded that silver nearest-neighbour interactions areresponsible for the absence of cationic motion.

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