Structural, optical, and thermoluminescence characterizations of 1 mol% Dy3+ion-activated Fluro Boro-phosphate glass for photonic devices

Abstract

A novel Fluro boro-phosphate host matrix doped with the 1 mol% of Dy3+ ions (50B2O3 + 20P2O5 + 10TiO2 + 10SrCO3 + 4BaF2 + 5BaCO3 + 1Dy2O3) was prepared using a conventional melt-quenching mechanism, and its structural characteristics were explored through the Powder-XRD, FT-IR, FT-Raman, EDAX and SEM spectroscopic analysis. The XRD spectrum of the glass confirmed its non-crystalline or amorphous structure. FT-IR and FT-Raman spectrum studies revealed that various borate and phosphate groups present with a variety of stretching and bending vibrations. Scanning Electron Microscope (SEM) and Energy Dispersive X-ray analysis (EDAX) analysis have been used to examine the surface morphology and the presence of elements, respectively in the prepared glass. The optical absorption spectrum was used to explore the electronic band structure through the measurements of optical band-gap energy and Urbach energy. The luminescence spectrum reveals the emission characteristics of Dy3+ ions due to the electric-dipole and magnetic-dipole transitions. It is found that the decay time of the 4F9/2 excited level at a concentration of 1 mol% Dy3+ in the glass matrix is tri-fit non-exponential. The CIE chromaticity coordinates and the concentration influence on Y/B intensity ratios were computed for the creation of white light from the luminescence spectrum. The present work also discusses the findings after figuring out the correlated color temperature associated (CCT) with the color purity (Pe). The Thermoluminescence (TL) characteristics and the kinetic parameters of the glass were studied after the γ-irradiation with a dose of 2 kGy. EPR investigation revealed the paramagnetic characteristics through the hyperfine structure of Dy3+ ions and the electron-hole pair formation upon irradiation in the glass matrix.