Abstract

Compounds in the BaxSr3−xTiNb4O15series withx = 0.0–3.0 were synthesised. Synchrotron X-ray diffraction data were collected for each member synthesised. Rietveld refinements were performed for all compositions. A composition-dependent phase transition between orthorhombic and tetragonal symmetries was found. Cation ordering was observed between barium and strontium atoms in the two distinctAsite cavities

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