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Abstract
A water-soluble polysaccharide, (Fr. I) isolated from the aqueous extract of an edible mushroom, Volvariella diplasia, is composed of d-glucose, d-mannose, and d-galactose in a molar ratio 3:1:1. Compositional analysis, methylation analysis, periodate oxidation study, Smith degradation, and NMR studies ( 1H, 13C, DQF-COSY, TOCSY, NOESY, ROESY, HMQC, and HMBC) revealed the presence of the following repeating unit in the polysaccharide: [Display omitted]
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