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Abstract
The presence of preferential OH-rotamers in tertiary alcohols dissolved in CCl 4 has been studied by means of the infrared absorption of the OH-stretching band. It appears that the position of the OH group in these molecules is related to the presence and the orientation of α- and β-alkyl groups. The oxygen lone pairs play a role as well. In some compounds the preferred rotamer proves to be the only one present.
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Schedule a callMore From: Spectrochimica Acta Part A: Molecular Spectroscopy
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