Abstract

Structural relaxation was examined by in situ Boson peak observation in 1BaO-2SiO2 glass with homogeneous nucleation tendency, in order to clarify the structural heterogeneity. The relation between the glass structure in the medium-range scale and nucleation feature is also discussed. From the results, it is predicted that a sheet-like structure with a network modifier in the resulting crystal is an essential condition for homogeneous nucleation.

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