Abstract
Structural features of 16 mononuclear monooxotantalum complexes have been considered. In eleven compounds (I–XI), the Та(V) atoms have different coordination polyhedra with CNTa from four and seven: a tetrahedron, octahedron, pentagonal bipyramid, and monocapped trigonal prism. Five TaO compounds (XII–XVI) contain pentahapto-bonded η5-С5Ме5 (η5-Ср*) and η5-С5Н4SiМе3 ligands. In complexes II–X, double bonded O(oxo) ligands are trans to О(Ln) or N(Ln) atoms.
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