Structural Features of Monomeric Octahedral Monooxo d2-Rhenium(V) Complexes [ReO(Ltrin)(Lmono)2] and [ReO(Ltrin)(Lbim)] with Oxygen Atoms of Tridentate Chelating (O, N, O) Ligands (Ltrin) (Review)

Abstract

Structural features of 22 mononuclear octahedral monooxo d2-Re(V) complexes with tridentate chelating (О, N, О) ligands (Ltrin)—[ReO(Ltrin)(Lmono)2] and [ReO(Ltrin)(Lbim)] (Lmono is a monodentate ligand, is a bidentate ligand)—have been considered. Conditions for selecting ligands that can be located trans to the multiply bonded O(oxo) ligand are discussed.