Abstract
This paper presents data on the mixed alkali effect in two fundamentally different systems: chalcogenide and oxide (phosphate). In the first system (Ag – Cu)0.44AsSe1.5, the predominantly ionic conductivity of silver-containing glasses is replaced by purely electronic in copper-containing, in the second - 0.5(Li2O-Na2O) – 0.4P2O5 – 0.1Nb2O5 carriers of electric current are alkaline ions and the extreme dependences of the electrical parameters associated with their joint migration.
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