Abstract
Residual dipolar coupling (RDC) has recently become increasingly important in organic structural determination due to their unique information content. This review provides a brief overview of the basic principle and general strategy in the application of RDC in the structure elucidation of organic molecule. The availability of various alignment media and pulse sequences were also discribed. In addition, the applications of RDCs for the constitution, configuration and conformation determination of natural or synthetic molecules were summarized to exemplify the practical application of the technique in recent years. Finally, the challenges and perspectives for future applications were also presented.
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