Structural, electrical and magnetic study of nanocrystalline Ti-substituted Zn–Mn ferrospinels

Abstract

Titanium substituted Zn–Mn ferrites were prepared by sol–gel route. Formation of single phase cubic spinel structure for all the compositions was confirmed from their X-ray diffraction studies. These ferrite samples existed as uniform and homogenous grain size as observed from scanning electron microscopy technique (SEM). The magnetic studies indicated that, the ferrimagnetic behavior increases with titanium substitution. Dielectric constant and complex impedance were measured as a function of frequency in the range 20Hz–1MHz. Frequency dependence of dielectric constant shows dielectric dispersion due to the Maxwell–Wagner type of interfacial polarization and impedance study reveals that the electrical conduction in the ferrites is by the interior of the grain boundaries. In general, the substitution of titanium plays an important role in changing the structural, magnetic and electrical properties of these ferrites.