Structural effects of titanium(IV) oxide encapsulated in a hollow silica shell on photocatalytic activity for gas-phase decomposition of organics

Abstract

TiO 2 particles encapsulated in hollow silica shells with controlled shell thicknesses were fabricated. Compared to naked TiO 2 without coverage by a hollow silica shell, all of these composites showed low levels of photocatalytic activity for gas-phase decomposition of acetone into CO 2. The activities over these composites tended to decrease with increase in thickness of the lateral silica shell. These results can be explained by a decrease in the diffusion of acetone with increase in thickness of the silica shell, leading to hampering of supply of the substrate to the surfaces of core TiO 2 particles. In contrast, for the overall photodecomposition of gaseous 2-propanol into CO 2, the presence of the lateral silica shell was found to be beneficial, i.e., the composite induced a high level of activity compared to the activity of naked TiO 2. The enhancement of activity for this reaction was likely to be due to condensation of the intermediate product of acetone in the void spaces, leading to an increase in the collision probability between acetone and the surface of the TiO 2 core.