Abstract
A coordination environment reminiscent of a paddle-wheel is exhibited by aryl groups about one of the two cesium ions in CsP(H)Dmp (Dmp=2,6-dimesitylphenyl; structure depicted on the right), which has now been synthesized and is found to exhibit Cs+ {Cs2 [P(H)Dmp]3 }- contact ion pairs in the solid state. In contrast, the analogous rubidium compound displays a Rb4 P4 cube as the central structural motif.
Published Version
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