Abstract
Reactions of trimethylphosphine or diphosphines with SbCl(3) in the presence of AlCl(3) or Me(3)SiSO(3)CF(3) give ligand stabilized stibenium and stibinidenium cations. The geometry at each antimony center reveals a variety of environments for antimony that describes new bonding and highlights new directions in the chemistry of the pnictogen elements.
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