Abstract
Solid-state structural transformation of TlI supramolecular polymer comprised from cubane-type thallium complex of [Tl4(μ3-4-BN)4] (1) (4-HBN=4-hydroxy benzonitrile) to AgI coordination polymer with three nuclear units of [Ag3(μ3-4-BN)2(μ4-4-BN)] (2) has been studied upon mechanochemical reaction of compound 1 with AgNO3.
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