Abstract
Stereospecific behavior of allyl derivatives and acetylenes in CuX π-complexes (X = Cl-, Br-, NO3-, BF4-, 1/2SiF62-, 1/2SO42-) is studied by X-ray diffraction analysis. The influence of donor atoms N, S, and O and of the Cu-X bond polarization on the π-complex formation is considered. The efficiency of Cu-(C=C) and Cu-(C≡C) π-interaction and specific behavior of mono- and disubstituted acetylenes with respect to Cu(I) are compared.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
