Abstract

The review surveys the main trends in the structural chemistry of clathrochelates: the determination of the crystal and molecular structures of various types of new complexes, their symmetry and functionality; the supramolecular organization and phase transitions of clathrochelate crystals; the structure—spectral parameter relationships and the deduction of the molecular structures; the use of X-ray diffraction data for explanation of the kinetic and thermodynamic parameters of the synthesis and decomposition of clathrochelates.

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