Abstract
The ternary selenide Pb6Sb6Se17 was synthesized hydrothermally from the binaries (PbSe and Sb2Se3) and crystallizes in the orthorhombic space group Pbam (a = 15.835(3), b = 24.043(5), c = 4.134(2)Å, Z = 2). The main building blocks of the crystal structure are ribbons made of square pyramidal [(Pb,Sb)Se5] groups running along [010].
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