Structural characterization of nylon 4 in the solid state by high-resolution solid-state 1H NMR spectroscopy

Abstract

High-resolution solid-state 1H NMR spectra of nylon 4 melt-quenched sample and single crystal sample in the solid state were measured in a wide range of temperatures from room temperature to 505K by using solid state 300MHz NMR with the FSLG-2 homo-nuclear dipolar decoupling method combined with high speed magic angle spinning method. From the experimental results, structural characterization on the crystalline and non-crystalline components was carried out. Further, intermolecular interaction between nylon 4 and water contained in the sample was discussed.