Structural Characterization of Different Asphaltenes of Kuwaiti Origin

Abstract

Asphaltenes obtained by precipitation from crude Kuwaiti oils have been analyzed by proton magnetic resonance (1H-NMR), carbon-13 nuclear magnetic resonance (13C-NMR) and Infrared (IR) spectral techniques. The molecular weight and elemental analysis were also determined. These combined analytical data were used for the characterization of these Kuwaiti oils. The asphaltenes molecular weights range from approximately 4200–6500 with an H/C ratio of 0.91–1.1 with an average 45–71% aromatic carbons. The average side chain length was of 4–6 carbons. It can also be concluded that the asphaltenes under investigation contain 5–9 sets of condensed aromatic rings joined together by bridges of alkyl chains or other hetero atoms and the average number of each of these sets of condensed aromatic rings is nearly 7. There are a number of alicyclic rings and condensed alicyclic rings in asphaltene. The IR spectra showed main molecular groups including OH, NH, SH, C=O and aliphatic and aromatic C-H′s.