Abstract
ESR spectra show the simultaneous presence of a planar trans and a nearly planar cis isomers in the 1:2 ratio for all S,O compounds Cu (R1R2N-CS-N-COR) 2 whereas an only isomer is present with the analogous S,N compounds. A strong tetrahedral distortion is observed when a bulky substituent is present on the nitrogen donor atom.
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