Structural characteristics and opto-electrical properties of in-situ synthesized polyaniline films

Abstract

In the present study, polyaniline (PAni) thin films have been deposited on glass substrates by in-situ chemical polymerization method using simple dip-coating technique and their opto-electrical properties have been studied. The structure of deposited films have been analysed with Fourier transform infrared (FTIR) and Raman spectroscopic techniques to investigate the effect of deposition times on the conjugation length, polaron/bipolaron concentrations and other molecular structure conformations. FTIR and Raman spectroscopy studies reveal increase in both the conjugation length and the polaron/bipolaron carrier concentration with increasing deposition time of the prepared PAni films. The optical properties and optical band-gap of the deposited films have been estimated through UV–visible spectroscopy. The optical band-gap of the deposited films has been found to decrease from 3.31 eV to 3.13 eV with increase in deposition time from 1.5 h to 2.5 h, and further it has been increased slightly to 3.19 eV for the PAni film deposited for 3 h. The electrical conductivity of the deposited films has been found to increase with decrease in optical band gap. The parameters estimated from FTIR, Raman, UV–visible spectroscopy and electrical measurements are in good agreement with each other. It has been observed that the optical and electrical properties of the deposited films depend on the conjugation length of PAni. The polymerization time of 2.5 h has been found to be optimum for obtaining PAni thin films with good electrical conductivity and low optical band gap.