Structural characterisation of Er–Si–Al–O–N glasses by Raman spectroscopy

Abstract

Er–Si–Al–O–N glasses have been prepared with cation ratio Er:Si:Al = 3.45:3:2 containing various amounts of nitrogen ( N = 0, 5, 8, 15 and 22 equiv.%). Glass properties such as microhardness, glass transition temperature and dilatometric softening temperature were measured and it was found that these properties increased linearly with increasing nitrogen content. Glasses were then characterised using Raman spectroscopy in order to obtain information about the structure of these glasses. Deconvolution of peaks in the Raman spectra of Er–Si–Al–O–N glasses revealed that, as nitrogen content increases then the proportion of Q 3 species decreases and there is a corresponding increase in the proportion of Q 4 species ( Q n : n = no. of bridging anions joining SiO 4 tetrahedra), confirming that nitrogen increases the crosslinking between individual tetrahedra via the transformation of Q 3 oxide species into Q 4 oxynitride species.