Abstract
The reaction of RPCl2 [R = (6-Me-2-pyridyl)(SiMe3)2C–] with LiAlH4 in Et2O gives the novel N-functionalised disecondary diphosphane compound [R(H)P–P(H)R] rather than the expected phosphorus dihydride complex RPH2; the meso and rac isomers of the diphosphane crystallise separately with the meso isomer being structurally authenticated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.