Abstract
The crystal structure of (Cs) 0.26(Rb) 0.74H(SO 4) 0.89(SeO 4) 0.11 (CsRbHSSe) has been determined by X-ray single-crystal analysis. This compound crystallizes in the space group Pc with unit cell dimensions a=14.733(4) A ̊ , b=4.6437(9) A ̊ , c=15.102(4) A ̊ , β=120.94(3)°, and Z=8. The refinement converged to R=0.0391 and wR 2=0.0964. The mixed compound CsRbHSSe is a chain-based structure. The Cs + and Rb + cations are intercalated between chains of HBO 4 − (B=S, Se) groups linked with O–H⋯O hydrogen-bonding. CsRbHSSe presents a new type of structural arrangement different from RbH(SO 4) 0.81(SeO 4) 0.19 (RbHSSe) and CsH(SO 4) 0.76(SeO 4) 0.24 (CsHSSe). Infrared (IR) and Raman spectroscopic studies were performed to confirm results of the radiocrystallographic method.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
